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  • Alkylamines (C1-C6)

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Alkylamines (C1-C6)

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Published: December 2011

  • Abstract
  • Table of Contents
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    Information
  • C1-C6 alkyl monoamines are important and well-established building blocks for several industrial products. Each individual C1-C6 alkylamine has its own set of applications, with the largest applications including the manufacture of solvents, pesticides, feed additives, water treating chemicals, and rubber processing chemicals. These C1-C6 monoamines are produced primarily from ammonia and an alcohol. The report includes the following products:

    • Methylamines (C1)
    • Ethylamines (C2)
    • Propylamines and isopropylamines (C3)
    • n-Butylamines and isobutylamines (C4)
    • Amylamines (C5)
    • Cyclohexylamines (C6)

    China is the largest consumer of C1-C6 alkylamines, mainly dimethylamine for DMF (dimethylformamide) because it has a large synthetic/artificial leather (polyurethane-based) market—an application that is comparatively miniscule in most other regions. Consumption of DMF in electronics, mainly in the manufacture of printed circuit boards, is a large market in Asia, especially Taiwan, the Republic of Korea and Japan. As a result, Asia accounted for over half of world consumption of C1-C6 alkylamines in 2007. China is forecast to remain the largest market for C1-C6 alkylamines in 2012; demand for solvents, rubber processing chemicals, pesticides and choline chloride (a feed additive) will experience rapid growth.

    The following pie chart shows world consumption of C1-C6 alkylamines:

    alkylamines

    China is the largest single producer and consumer of C1-C6 alkylamines.

    Methylamines accounted for about 75% of world demand, mostly for production of solvents such as dimethylformamide (DMF), dimethylacetamide (DMAc) and N-methylpyrrolidone (NMP). DMF is the largest single derivative of methylamines.

    China's consumption of C1-C6 alkylamines, mainly dimethylamine for DMF because of a large synthetic/artificial leather (polyurethane-based) market—an application that is comparatively miniscule in most other regions. Consumption of DMF in electronics, mainly in the manufacture of printed circuit boards, is a large market in Asia, especially Taiwan, the Republic of Korea and Japan. As a result, Asia accounted for about 59% of world consumption of C1-C6 alkylamines in 2010. China is forecast to remain the largest market for C1-C6 alkylamines in 2016; demand for solvents, rubber processing chemicals, pesticides and choline chloride (a feed additive) will experience rapid growth.

    Consumption of C1-C6 alkylamines fluctuates annually, especially as related to demand for pesticides, which varies according to weather and planted acreage. Some C1-C6 alkylamines, such as isopropylamine, have large export volumes. However, international trade is not a major factor; world exports accounted for approximately 11.5% of production in 2010. Several C1-C6 alkylamine derivatives have substantial export volumes; examples include NMP and DMF.

    The market is at risk for consolidation. Additional planned capacity, if commissioned during 2010–2016, will likely result in the shutdown of older less-efficient plants. Areas at risk for plant shutdowns or reduced production include North America, Europe and Asia. Additionally, some announced projects are at risk of being cancelled or delayed because of market conditions, project costs or labor costs.

  • Table of Contents

    Summary
    Introduction
    Manufacturing Processes
    Alcohol-Amine Reaction
    Aldehyde-Amine and ketamine hydrogenation Reaction
    Nitrile Reduction
    Ritter Reaction
    Direct Amination
    Hydrogenation of Anilines
    Reaction of alkyl halides with amines (or ammonia)
    Environmental issues
    Supply and Demand by Region
    United States
    Producing Companies
    Production
    Consumption
    Methylamines
    Methylamine
    Dimethylamine
    Trimethylamine
    Ethylamines
    Ethylamine
    Diethylamine
    Triethylamine
    Propylamines
    n-Propylamines
    Isopropylamines
    Butylamines
    n-Butylamine
    Di-n-butylamine
    Tri-n-butylamine
    Isobutylamines
    tert-Butylamine
    Amylamines
    Cyclohexylamines
    Cyclohexylamine
    N-Alkylcyclohexylamines
    Allyl and Methallylamines
    Price
    Trade
    Imports
    Exports
    Canada
    Salient Statistics
    Consumption
    Trade
    Mexico
    Producing Companies
    Salient Statistics
    Consumption
    Trade
    Imports
    Exports
    Brazil
    Producing Companies
    Salient Statistics
    Production
    Consumption
    Trade
    Other Central and South America
    Salient Statistics
    Consumption
    Western Europe
    Producing Companies
    Production
    Consumption
    Methylamines
    Methylamine
    Dimethylamine
    Trimethylamine
    Ethylamines
    Ethylamine
    Diethylamine
    Triethylamine
    Propylamines
    n-Propylamines
    Isopropylamines
    Butylamines
    Cyclohexylamines
    Price
    Trade
    Imports
    Exports
    Central and Eastern Europe
    Producing Companies
    Production
    Consumption
    Methylamines
    Czech Republic
    Hungary
    Poland
    Russia
    Ethylamines
    Czech Republic and Slovakia
    Hungary
    Poland
    Russia
    Propylamines
    Hungary
    Russia
    Butylamines
    Cyclohexylamines
    Czech Republic and Slovakia
    Hungary
    Russia
    Trade
    Japan
    Producing Companies
    Production
    Consumption
    Methylamines
    Methylamine
    Dimethylamine
    Trimethylamine
    Ethylamines
    Propylamines
    Butylamines
    n-Butylamines
    tert-Butylamine
    Cyclohexylamines
    Price
    Trade
    Imports
    Exports
    Other Asia
    Producing Companies
    Salient Statistics
    Consumption
    China
    Salient Statistics
    Trade
    India
    Salient Statistics
    Trade
    Indonesia
    Salient Statistics
    Trade
    Republic of Korea
    Salient Statistics
    Trade
    Taiwan
    Salient Statistics
    Trade
    Africa, Middle East and Oceania
    Producing Companies
    Salient Statistics
    Consumption
    South Africa
    Saudi Arabia
    Turkey
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